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    請使用永久網址來引用或連結此文件: https://irlib.pccu.edu.tw/handle/987654321/48792


    題名: Fabrication of a highly sensitive flexible humidity sensor based on Pt/polythiophene/reduced graphene oxide ternary nanocomposite films using a simple one-pot method
    作者: Tsai, MS (Tsai, Meng-Shian)
    Su, PG (Su, Pi-Guey)
    Lu, CJ (Lu, Chia-Jung)
    貢獻者: 化學系
    關鍵詞: Flexible humidity sensor
    polythiophene
    Pt
    reduced graphene oxide
    nanocomposite
    日期: 2020-12-01
    上傳時間: 2020-11-06 14:04:35 (UTC+8)
    摘要: A novel, flexible humidity sensor based on ternary nanocomposite films of Pt nanoparticles, polythiophene, and reduced graphene oxide (Pt/polythiophene/RGO) was fabricated using a simple one-pot redox synthesis. First, 2-thiophene methanol (2-TPM) was allowed to react with PtCl42- ions via an oxidative polymerization process, which released electrons that simultaneously reduce the PtCl42- ions and GO to Pt nanoparticles and RGO, respectively. The effects of the amounts of added PtCl42- ions and RGO on the electrical, flexibility, and humidity-sensing properties of the Pt/polythiophene/RGO ternary nanocomposite films were investigated. The Pt/polythiophene/RGO ternary nanocomposite films were characterized by using the Fourier transform infrared spectroscopy (FTIR), Raman, atomic force microscopy (AFM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). A Pt/polythiophene/RGO ternary nanocomposite film containing 30 mg of Pt and 0.1 g of RGO exhibited the greatest flexibility, sensitivity, and long-term stability. This flexible humidity sensor also demonstrated a wide range of working humidities, an acceptable linearity, a small hysteresis, a short response/recovery time, and a weak temperature dependence. We used complex impedance spectra to explain the humidity-sensing mechanism of the flexible sensor based on Pt/polythiophene/RGO ternary nanocomposite films and thus found that the ions (H3O+) in this system dominate the conductance process of the sensor.
    關聯: SENSORS AND ACTUATORS B-CHEMICAL 卷冊: 324 文獻號碼: 128728
    顯示於類別:[化學系所] 期刊論文

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