English  |  正體中文  |  简体中文  |  全文筆數/總筆數 : 46833/50693 (92%)
造訪人次 : 11846013      線上人數 : 402
RC Version 6.0 © Powered By DSPACE, MIT. Enhanced by NTU Library IR team.
搜尋範圍 查詢小技巧:
  • 您可在西文檢索詞彙前後加上"雙引號",以獲取較精準的檢索結果
  • 若欲以作者姓名搜尋,建議至進階搜尋限定作者欄位,可獲得較完整資料
  • 進階搜尋
    主頁登入上傳說明關於CCUR管理 到手機版


    請使用永久網址來引用或連結此文件: https://irlib.pccu.edu.tw/handle/987654321/23126


    題名: 乙二胺四乙酸二鈉鹽、乙二胺四乙酸鈣二鈉及L-半胱氨酸鹽酸鹽抗氧化劑於超臨界二氧化碳中溶解度的測量與分析
    作者: 謝欣霖
    貢獻者: 化學工程與材料工程學系
    關鍵詞: 抗氧化劑
    Antioxidant
    溶解度
    Solubility
    超臨界二氧化碳
    Supercritical carbon dioxide
    日期: 2012
    上傳時間: 2012-10-11 09:15:30 (UTC+8)
    摘要: 本研究利用半流動式超臨界流體實驗設備,對三種臺灣核准的抗氧化劑,乙二胺四乙酸二鈉鹽(EDTA Disodium Salt)、乙二胺四乙酸鈣二鈉(EDTA Calcium Disodium)以及L-半胱氨酸鹽酸鹽(L-cysteine Hydrochloride)進行溶解度實驗。
    乙二胺四乙酸二鈉鹽量測溫度為308.2到318.2K,壓力範圍為10到22 MPa。乙二胺四乙酸鈣二鈉量測溫度為308.2到318.2K,壓力範圍為12到24 MPa。L-半胱氨酸鹽酸鹽量測溫度為308.2到318.2K,壓力範圍為12到24 MPa。
    實驗結果顯示,三種抗氧化劑於超臨界二氧化碳中的溶解度莫耳分率均介於10-7到10-6 mol%之間。本研究也同時利用了兩條半經驗方程式Mendez-Santiago and Teja Model(MST Model)和Chrastil Model,進行溶解度數據回歸,並藉由平均絕對相對偏差(Average Absolute Relative Deviation AARD)來判斷本實驗結果之合理性。

    The solubilities for three anti-oxidants permitted in Taiwan of EDTA Disodium Salt, EDTA Calcium Disodium and L-cysteine Hydrochloride in supercritical carbon dioxide were measured in this study using a semi-flow type apparatus.
    For EDTA Disodium Salt, the experiment data were taken at 308.2 to 318.2K and the pressure range from 10 to 22MPa; for EDTA Calcium Disodium, at 308.2 to 318.2K and the pressure range from 12 to 24MPa; for L-cysteine Hydrochloride, at 308.2 to 318.2K and the pressure range from 12 to 24MPa.
    According to the measured results, the solid solubilities of these three compounds in supercritical carbon dioxide were between 10-7 to 10-6 mol %.Meanwhile, the regression has been made by using using semi-empirical equation presented by Chrastil, and that presented by Mendez-Santiago and Teja(MST), and with the average absolute relative deviation (AARD), the result of this research could be determined.
    顯示於類別:[化學工程與材料工程學系暨碩士班] 博碩士論文

    文件中的檔案:

    檔案 描述 大小格式瀏覽次數
    index.html0KbHTML453檢視/開啟


    在CCUR中所有的資料項目都受到原著作權保護.


    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library IR team Copyright ©   - 回饋