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    請使用永久網址來引用或連結此文件: https://irlib.pccu.edu.tw/handle/987654321/21118


    題名: Rapid Synthesis of Bundled Tungsten Oxide Nanowires by Microwave Plasma-Enhanced Chemical Vapor Deposition and Their Optical Properties
    作者: Hsieh, YT (Hsieh, Yun-Tsung)
    Hsueh, SH (Hsueh, Sen-Hong)
    Chen, US (Chen, Uei-Shin)
    Huang, MW (Huang, Meng-Wen)
    Shih, HC (Shih, Han C.)
    貢獻者: 化材所
    關鍵詞: FIELD-EMISSION PROPERTIES
    LOW-TEMPERATURE
    NANOTUBES
    ARRAYS
    ULTRAVIOLET
    NANORODS
    日期: 2010
    上傳時間: 2011-12-15 15:47:36 (UTC+8)
    摘要: In recent years, the synthesis of one-dimensional nanomaterials has assumed considerable importance because of the potential applications of these nanomaterials especially in nanodevices. In this study, bundled tungsten oxide (W(18)O(49)) nanowires having diameters of 25-60 nm and lengths of several micrometers were fabricated on Si substrates within 1.5 min by microwave plasma-enhanced chemical vapor deposition (MPECVD). The crystal structure, morphology, and chemical composition of these nanowires were characterized by scanning electron microscopy, X-ray diffraction, transmission electron microscopy, energy-dispersive X-ray spectroscopy, and cathodoluminescence (CL) spectrometry. The growth of the W(18)O(49) nanowires occurred along the [010] plane. Because no catalysts were used, it was suggested, and then analytically confirmed, that the vapor-solid mechanism was suggested for this growth process; this has been confirmed analytically. An orange emission was observed in the CL spectra, suggesting that the W(18)O(49) nanowires exhibited a redshift, resulting from the presence of significant O deficiencies. In this manner, our overall results demonstrate that MPECVD is a highly effective and suitable method for the fabrication of W(18)O(49) nanowires. (C) 2010 The Electrochemical Society. [DOI:10.1149/1.3459906] All rights reserved.
    顯示於類別:[化學工程與材料工程學系暨碩士班] 期刊論文

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